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October 2, 2014

EPA Proposes SNUR for Nonylphenols and Nonylphenol Ethoxylates

The ACTA Group

On October 1, 2014, the U.S. Environmental Protection Agency (EPA) proposed a Significant New Use Rule (SNUR) for 15 related chemical substances commonly known as nonylphenols (NP) and nonylphenol ethoxylates (NPE). For 13 NPs and NPEs, EPA would designate any use as a “significant new use,” and for two additional NPs, EPA would designate that any use other than use as an intermediate or use as an epoxy cure catalyst would constitute a “significant new use.” Persons subject to the SNURs would be required to notify EPA at least 90 days before they manufacture (including import) or process any of these 15 chemical substances for a significant new use. Comments are due December 1, 2014. More information is available online.

EPA is proposing to designate any use of the 13 NPs and NPEs listed below in Table 1 as a significant new use, and any use other than use as an intermediate or use as an epoxy cure catalyst as a significant new use of the two additional NPs listed below in Table 2:

Table 1. NPs and NPEs for which Any Use Is a Significant New Use

Chemical NameChemical Abstracts Index NameChemical Abstracts Service Registry Number (CASRN)NP or NPE
4-nonylphenolPhenol, 4-nonyl-104-40-5NP
2-[2-[2-[2-(4- nonylphenoxy)ethoxy]
Ethanol, 2-[2-[2-[2-(4- nonylphenoxy)ethoxy]
α (Nonylphenyl)-ω-hydroxy-poly(oxy-1,2- ethanediyl)Poly(oxy-1,2-ethanediyl), α(nonylphenyl)- ω-hydroxy-9016-45-9NPE
Ethanol, 2-[2-(4-nonylphenoxy)ethoxy]-20427-84-3NPE
NonylphenolPhenol, nonyl-25154-52-3NP
(oxy-1,2- ethanediyl)
Poly(oxy-1,2-ethanediyl), α-(4-nonylphenyl)- ω-hydroxy-26027-38-3NPE
2-[2-[2-[2-[2-[2-[2-[2-[2- (Nonylphenoxy)ethoxy]ethoxy]
ethoxy]ethoxy]ethox y]ethoxy]
3,6,9,12,15,18,21,24-Octaoxahexacosan-1-ol, 26-(nonylphenoxy)-26571-11-9NPE
2-[2-(Nonylphenoxy)ethoxy]ethanolEthanol, 2-[2-(nonylphenoxy)ethoxy]-27176-93-8NPE
2-[2-[2-[2-[2-[2-[2-[2- (nonylphenoxy)ethoxy]ethoxy]
ethoxy]ethoxy]ethox y]ethoxy]
3,6,9,12,15,18,21-Heptaoxatricosan-1-ol, 23- (nonylphenoxy)-27177-05-5NPE
2-[2-[2-[2-[2-[2-[2-[2-[2-[2- (nonylphenoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethox y]ethoxy]ethoxy]ethoxy]ethoxy]ethanol3,6,9,12,15,18,21,24,27-Nonaoxanonacosan-1- ol, 29-(nonylphenoxy)-27177-08-8NPE
2-(Nonylphenoxy)ethanolEthanol, 2-(nonylphenoxy)-27986-36-3NPE
α-(Isononylphenyl)-ω-hydroxy-poly(oxy-1,2- ethanediyl)Poly(oxy-1,2-ethanediyl), α-(isononylphenyl)- ω-hydroxy-37205-87-1NPE
α-(2-Nonylphenyl)-ω-hydroxy-poly(oxy-1,2- ethanediyl),Poly(oxy-1,2-ethanediyl), α-(2- nonylphenyl)-ω-hydroxy-51938–25–1NPE

Table 2. NPs for which Any Use Other Than as an Intermediate or Epoxy Cure Catalyst Is a Significant New Use

Chemical NameChemical Abstracts Index NameCASRNNP or NPE
4-nonylphenol, branchedPhenol, 4-nonyl-, branched84852-15-3NP
2-nonylphenol, branchedPhenol, 2-nonyl-, branched91672-41-2NP

The proposed SNUR would apply to the uses that are not ongoing at the time of the proposed rule. Uses not ongoing at the time of the proposal would be designated significant new uses in the final SNUR. EPA states that it is specifically requesting comment on whether it has correctly identified the current and ongoing uses of the 15 NPs and NPEs covered by this proposed rule. According to the Federal Register notice, EPA is particularly interested in whether anyone is currently using these chemicals in a manner that is not described in this proposal.

Of the 13 linear NPs and NPEs listed in Table 1, EPA states that 12 of the chemical substances were not reported to the 2012 Chemical Data Reporting (CDR) Rule. One of the 13 substances was reported to the 2012 CDR, but, according to EPA, “the available information indicates that the chemical substance is not currently being manufactured or is otherwise used or distributed in commerce.” The two branched NPs listed in Table 2 are not in use except as intermediates and epoxy cure catalysts. EPA states that, based on the “reasonably anticipated manner and methods of manufacturing, processing, distribution in commerce, and disposal of these chemical substances,” it is concerned that future manufacturing or processing could have the potential to increase significantly the magnitude and duration of environmental exposures. EPA determined that “individual evaluation of the activities associated with those new uses is warranted to allow the Agency to determine whether any controls are necessary before such manufacturing (including importing) or processing starts or resumes.” EPA specifically requests comment “on all aspects of this proposed rule, including the commercial production of linear forms of NPs and NPEs, as well as any ongoing uses of the subject chemical substances.”


Although the NPs and NPEs are a class of chemicals known to be persistent and toxic in the environment, what may be new about the proposal is the way that EPA apparently relied exclusively upon a narrow data set — the 2012 CDR and two databases (Household Products Database and Consumer Products Information Database) — as the basis for determining that 13 of the chemicals are not in production. Accordingly, EPA has proposed an “any use” SNUR for each identified chemical. There is no indication in the record that suggests EPA conducted other Internet searches, e.g., using the CASRN to search for commercial availability information, Material Safety Data Sheets (MSDS), or other information that might indicate continued commercial availability. A quick CASRN search of 4-nonylphenol (CASRN 104-40-5) showed a number of hits, including, among others, on the website, which reported 70 global suppliers with 15 located in the U.S. On the other hand, the chemical identified as CASRN 7311-27-5 showed only one global supplier (from China) on this site. The search for the chemical CASRN 9016-45-9 showed MSDSs from a number of well-known domestic chemical companies and many other hits that seemed indicative of continued commercialization. Similar searches were conducted for other chemicals in the proposal with similar results, for all but one of the chemicals, which had no hits.

EPA’s confidence in concluding 13 chemicals are commercially dead, based on the limited due diligence revealed in the record, is unwarranted. While EPA appears to have a basis for concluding that production/importation in excess of the CDR trigger for 2012 (25,000 lbs at a site) is known not to have occurred in the CDR reporting year, the leap to a proposed conclusion that the 13 chemicals are no longer in commerce — and thus justifying an “any use” SNUR — is very shaky. Further, there is no discussion in the notice of the limitations in the 2012 CDR (site-specific volume trigger with no reporting required if trigger is not met) and no background discussion of reporting under other earlier Inventory Update Rule (IUR) cycles. Additional reporting data points (e.g., reporting under the IUR, results of contemporaneous Internet searches for indicators of commercial availability) could provide potentially relevant information given that the 2012 CDR reporting only covered the year 2011. Also, in the case of other proposed SNURs (e.g., Perfluorooctane Sulfonate (PFOS), Long Chain Perfluorinated Chemicals (PFCs), Polybrominated diphenylethers (PBDEs), among others), EPA cited industry commitments to phase-out certain chemicals/uses, or statements indicating that production or a use has ceased, as a basis for the proposal. No such commitments or statements appear in the proposed SNUR.

While EPA has developed a number of innovative ways to use its SNUR authority to regulate problematic existing chemicals over past years, we find it somewhat surprising that EPA in this case has proceeded without undertaking what could be considered reasonable due diligence in supporting its consideration of the Section 5(a)(2) factor concerning production. In conducting a rather anemic investigation, EPA has shifted the entire burden on industry to disprove its contentions. While we acknowledge that the Agency’s resources are limited and valuable, the same is true of industry’s available resources. Further, the quick results that we obtained through CASRN searches on a few of the chemicals in the rule provide what could be considered a prima facie refutation of the SNUR “any use” trigger if not the entire rulemaking premise of using CDR data in the way that EPA has done.

These deficits make it all the more important for companies with interest in NPs and NPEs at issue to review the proposal carefully. It will be essential to consider their commercial status and, as appropriate, comment on the proposal and ensure EPA is aware of any ongoing production, processing, or uses. We particularly alert processors and users of such surfactant chemicals to consider their situation, given that they are not otherwise required to consider the specific chemicals and volumes they obtain and use for purposes of reporting under the CDR, as is the case for manufacturers and importers.

While we may agree that EPA’s approach represents the minimum level of effort to support a “more than X pounds at a site” SNUR trigger for the 13 chemicals (where X is some number satisfying the “significant new” concept that appears in Section 5(a)(2)), it would have been preferable, and perhaps more legally defensible, for EPA to have done more to support its case before declaring the commercial death of 13 chemicals and burdening industry to the extent it has. Internet searches using a CASRN are neither difficult nor expensive, and even this minimal effort would yield potentially relevant information and demonstrate a due diligence that appears to be lacking.